science-softCon uv/vis+ spectra data base;	www.uv-spectra.de, (C) science-softcon 2019

Substance: silyl radical			Other Names: 

Formula: SiH3					CAS-No.: 13765-44-1

Study: uv absorption spectrum, kinetics


Authors: A.V. Baklanov, L.N. Krasnoperov

Title: UV absorption spectrum and rate constant for self-reaction of silyl radicals

Journal/Source: J. Phys. Chem. A, 105, 4917-4922, (2001); DOI: 10.1021/jp004198l


Data: table, diagram 

Energy/Wavelength range: 206.4 - 255.8 nm

Resolution: 

Temperature: 300 K

Temperature dependence: no

Pressure/Concentration: buffer gas pressure range (1-100 bar, He)

Phase: gas

pH:


Comments: The UV absorption of silyl radical has maximum at 218 nm with the absorption cross-section, 
sigma SiH3(218 nm) = (2.01 ± 0.11) × 10-17 cm2 molecule-1.

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