science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: acetyl cyanide				Other Names: pyruvonitrile

Formula: C3H3NO; CH3COCN				CAS-No.: 631-57-2

Study: photodissociation, UV absorption spectra


Authors: A. Furlan, H.A. Scheld, J.R. Huber

Title: The two competitive photodissociation channels in cyano carbonyls (NCC(O)X, X = CH3, CH(CH3)2, C(CH3)3, OCH3) at 193 nm. A study by photofragment translational energy spectroscopy

Journal/Source: J. Phys. Chem. A, 104, 1920-1929, (2000); DOI: 10.1021/jp9934836


Data: table, diagram

Energy/Wavelength range: 190 - 420 nm

Resolution: 0.2 nm

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration:

Phase:

pH:


Comments: The photodissociation of a series of four cyano carbonyl compounds NCC(O)X with X = methyl, isopropyl, tert-butyl, and 
methoxy was studied after excitation at 193 nm using photofragment translational energy spectroscopy.

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