science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: peroxyacetyl nitrate				Other Names: nitroethaneperoxoate; ethanoic nitric, PAN

Formula: CH3COOONO2					CAS-No.: 2278-22-0

Study: photolysis, quantum yields

                
Authors: T.L. Mazely, R.R. Friedl, S.P. Sander

Title: Quantum Yield of NO3 from Peroxyacetyl Nitrate Photolysis

Journal/Source: J. Phys. Chem. A, 101 (38), 7090–7097, (1997); DOI: 10.1021/jp971298r


Data: 

Energy/Wavelength range: 248 nm

Resolution: 

Temperature: 

Temperature dependence: 

Pressure/Concentration: 

Phase: gas

pH:


Comments: Peroxyacetyl nitrate (PAN) vapor was photolyzed at 248 nm and the NO3 photoproduct was detected by laser-induced fluorescence.
The average of data collected over a range of total pressures, precursor concentrations, and buffer gases was 0.3 ± 0.1 for the NO3 quantum yield, 
where the quoted statistical uncertainty represents two standard deviations.

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